Total alkalinity is closely associated with pH but rather than a measure of hydrogen ion concentration it is a measure of the ability of a solution to neutralize hydrogen ions. Expressed in parts per million (ppm), total alkalinity is the result of alkaline materials including carbonates, bicarbonates and hydroxides - mostly bicarbonates. This acid neutralizing (buffering) capacity of water is desirable because it helps prevent wide variations in pH whenever small amounts of acid or alkali are added to the pool. Total alkalinity is a measure of water's resistance to change in pH.